All Clean Natural Wipes SDS

SAFETY DATA SHEET
SECTION 01 - PRODUCT AND COMPANY IDENTIFICATION
Product Identifier:
Product Code:
Other Means of Identification:
Cas Number
Product Use and Restrictions on use:
Supplier Identifier:
24-hour Emergency Phone:
TDG Emergency Response Plan: NWB Emergency Response Assistance Canada (ERAC):
All Clean Natural Hand Sanitizing Wipe (Wipe) – WHO Formula
Hand Sanitizer (Wipe) Antiseptic Skin Cleanser Ethanol 64-17-5
Hand Sanitizer/ Antiseptic skin cleanser
Do not use on children/infants less than 2 years of age (unless directed by a doctor/physician/health care practitioner/health care provider/health care professional).
All Clean Natural Ltd. 5310 1st Street SW Calgary, AB, T2H 0C8 (403) 455-9959
CANUTEC (24HR EMERGENCY TELEPHONE) (613) 996-6666
ERP 2-2063
1-800-265-0212
SECTION 02 - HAZARD IDENTIFICATION
Flammable Liquid : Category 3 Eye Irritation Category : 2A
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Signal word
Hazard statements (GHS-CCOHS)
Precautionary statements
: Warning
: H225 - Highly flammable liquid and vapor
: H319 - Causes serious eye irritation and remove contact lenses
: P210 – Keep away from heat, hot surfaces, open flames, sparks. – No smoking
: P233 - Keep container tightly closed
: If in eyes – Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue to rinse. If eye irritation persists, seek medical advice/attention.
: In case of fire – Use dry sand, dry chemical or alcohol resistant foam for extinction.
: Store in a well-ventilated place. Keep cool
Storage
Other Hazards:
: Not known
SECTION 03: COMPOSITION/ INFORMATION ON INGREDIENTS
Mixture Names
CAS-No
%
Ethanol Hydrogen Peroxide Glycerine Water
SECTION 04: FIRST AID MEASURES
Eye Contact:
64-17-5 7722-84-1 56-81-5 7732-18-5
69.00-80.00 0.125 1.45 Balance
When using this product avoid contact with eyes. If contact occurs, rinse thoroughly with water. Stop use and ask/consult a health care professional if irritation develops.
Inhalation:
Remove the victim into the fresh air. If difficulty breathing persists, seek medical attention.
Ingestion:
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Rinse mouth with water, do not induce vomiting. Call the Poison Information Centre (1-866-454-1212) SK, Canada. Consult a doctor/medical professional if you feel unwell.
Ingestion of Large Quantities:
Take individual immediately to hospital.
Note to Physician:
Treat Symptomatically.
SECTION 05: FIRE FIGHTING METHODS
Suitable extinguishing media Unsuitable extinguishing media
: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
: High volume water jet.
Specific hazards arising from the hazardous product (e.g., hazardous combustion products):
Fire Hazard : Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of
vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas.
Hazardous Combustion Products : Carbon Oxides
Special protective equipment and precautions for firefighters:
Specific Protective equipment for fire-fighters Specific Extinguishing methods
SECTION 6: ACCIDENTAL RELEASE MEASURES
: Use personal protective equipment.
: Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes.
Personal precautions, protective equipment and emergency procedures:
Protective equipment
Small Spill Large spill
: Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Wear appropriate protective equipment such as gloves, safety goggles, and coveralls when handling in bulk.
: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. : Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.
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Methods and materials for containment and cleaning up:
Emergency procedures
Environmental precautions Cleaning procedure
SECTION 07: HANDLING AND STORAGE
: Mark the danger area. Consider evacuation. Stop engines and no smoking. No naked flames or sparks. Spark- and explosion- proof of appliances and lighting equipment. Keep containers closed.
: Do not allow contact with soil, surface, or ground water.
: Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material, or otherwise, contain material to ensure run off does not reach a waterway.
7.1 Precautions for Safe Handling
Precautions for safe handling
Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Keep away from fire, sparks, and heated surfaces.
7.2 Conditions for Safe Storage (including incompatible materials)
Keep away from heat and sources of ignition. Keep in a cool, well-ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers.
Others
Good personal hygiene practices are suggested, such as abstaining from eating, drinking and smoking in the workplace
SECTION 08: EXPOSURE CONTROL/ PERSONAL PROTECTION
8.1 Control Parameters Occupational Exposure Guidelines, Limits, and the Source of Those Values
Exposure limits: Ethanol
CAS-No.
64-17-5
Form of Exposure TWA
Permissible Concentration 1,000 ppm 1,000ppm 1,900 mg/m3 1,000 ppm 1,900 mg/m3
Basis
ACGIH NIOSH REL OSHA Z1
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Glycerin Hydrogen Peroxide
56-81-5 7722-84-1
TWA TWA
15mg/m3 (total) OSHA 5mg/m3 PEL
1ppm (1.4mg/m3) NIOSH REL
1ppm (1.4 mg/m3) OSHA PEL
8.2 Appropriate Engineering Controls
Engineering Controls
Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
8.3 Individual Protection Measures (e.g. personal protective equipment).
Personal Protective Equipment (PPE) Hand Protection
Skin Protection
Respiratory Protection
Hygiene Measures
8.4 Exposure Limits
Ingredients
Ethanol
Hydrogen Peroxide Glycerin Water
No special protective equipment required
Exposure Limit ACGIH
1000 ppm TLV-TWA
TWA-1.0 PPM
TWA- 10mg/m3 --
Exposure Limit OSHA 1000 ppm TWA
unknown
unknown unknown
Immediately Dangerous to Life or Health IDLH
3300 ppm
TLV BASIS- Eye, URT, & Skin Irr.
TLV BASIS- URT irr Oral LD50 (Rat)> 90ml/kg
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES
Physical and chemical properties:
Appearance (physical state, colour, etc.) Odour
Odour threshold
Boiling point
pH
Melting point
Freezing point
Volatility
Lower flammability limit Upper Flammability Limit Flashpoint
Evaporation rate
Vapour pressure
Vapour density
: Gel/Translucent
: Typical lower alcohol odour : No data available
: No data available
: 7.0-8.5
: No data available
: No data available
: No data available
: No data available
: No data available
: 23°C closed up
: No data available
: No data available
: No data available
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Density Solubility
Partition coefficient - n-octanol/water Auto-ignition temperature Decomposition temperature
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability and reactivity:
Chemical stability
Possibility of hazardous reactions
Conditions to avoid (e.g., static discharge, shock, or vibration)
Incompatible materials
Hazardous decomposition products
SECTION 11: TOXICOLOGICAL INFORMATION
Routes of exposure:
Routes of Entry
Inhalation Ingestion
Skin contact Eye contact
: 0.833-0.840 @ 20°C
: Dissolved in water and alcohol
: No data available
: No data available
: No data available
: No data available
: Stable under normal conditions
: No dangerous reaction known under conditions of normal use
: Heat, flames and sparks.
: Strong acids. Strong bases
: Fumes. Carbon monoxide. Carbon dioxide. May release flammable gases.
: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
: Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use.
: Health injuries are not known or expected under normal use. : Causes serious eye irritation, redness, pain
Symptoms related to the physical, chemical and toxicological characteristics:
No symptoms known or expected.
Delayed and immediate effects, and chronic effects from short-term and long-term exposure:
No symptoms known or expected
Numerical measures of toxicity, including acute toxicity estimates (ATEs):
Acute oral toxicity IARC
OSHA
Health injuries are not known or expected under normal use. No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
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NTP
STOT-single exposure
SECTION 12: ECOLOGICAL INFORMATION
Ecological information:
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
The substance or mixture is not classified as specific target organ toxicant, single exposure
Ingredients
Environmental Effects Ethanol
Ecotoxicity- Fish Species Data
LC 50/96 Hour
Oncorhynchus mykiss>10,000 mg/l
Toxicity to Aquatic Plants
Growth inhibition/96 Hours Chlorella vulgaris 1000 mg/l
-
Toxicity to Micro Organisms
Harmful to aquatic life. Pseudomonas Putida 6,500 mg/l Inhibition
of cell growth
Other Adverse Effects
BOD 740-840 mg/g
Hydrogen Peroxide
Glycerin
Water - - - -
TWA-1.0 PPM, TWA-10mg/m3
-
-
-
-
-
SECTION 13: DISPOSABLE CONSIDERATIONS
13.1 Information on Safe Handling for Disposal and Methods of Disposal, Including any Contaminated Packaging.
Disposal Methods
The product should not be allowed to enter drains, water courses or the soil. Where possible, recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.
Disposal Considerations
Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers.
RCRA – Resource Conservation and Recovery Authorization Act: Hazardous Waste
D001 (ignitable)
SECTION 14: TRANSPORTATION INFORMATION
TDG (Canada)
UN number
Description of the goods Transport hazard class(es) Packing group
: UN1170
: ETHANOL Hand Sanitizer : Primary Class -3
: III
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Environmental Hazards Transport in bulk, if applicable
IMDG/IMO
UN number
Description of the goods Marine Pollutant:
SECTION 15: REGULATORY INFORMATION
: No
: 242 (49 CFR 173.xxxx)
: UN- 1170 Class: 3 Packing Group: II : ETHANOL Hand Sanitizer
: No
Safety, health and environmental regulations specific to the product:
CERCLA
SARA 304 Extremely Hazardous Substances Reportable Quantity
SARA 311/312 Hazards SARA 302
SARA 313 California Prop 65
SECTION 16: OTHER INFORMATION
NFPA Diamond for Ethanol
: This material does not contain any components with a CERCLA RQ.
: This material does not contain any components with a section 304 EHS RQ.
: Fire hazard acute health hazard.
: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
: SARA 313: This Material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
: This product does not contain any chemicals known to the State of California to cause cancer, birth or any other reproductive defects.
NFPA Health Hazard: 2 -Moderate
NFPA Fire Hazard: High
NFPA Physical Hazard: 0- Not Significant, 1=Slight
Additional Information: This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contain all the information required by the CPR. Disclaimer: NOTICE TO READER: All Clean Natural Ltd. expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or information provided herein, and shall under no circumstances be liable for incidental or consequential damages. Do not use ingredient information and/or ingredient percentages in this MSDS as a product specification. For product specification information refer to a
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Product Specification Sheet and/or a Certificate of Analysis. These can be obtained from All Clean Natural Ltd. All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources. While the information is believed to be accurate, All Clean Natural Ltd. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond All Clean Natural Ltd’s control and therefore users are responsible to verify this data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the publication or use of, or reliance upon, information contained herein. This information relates only to the product designated herein and does not relate to its use in combination with any other material or in any other process.
Note: Information in this SDS is from available published sources and is believed to be accurate. All Clean Natural Ltd. assumes no liability resulting from the use of this SDS. The responsibility to provide a safe workplace remains with the user. Note: The responsibility to provide a safe workplace remains with the user.
Preparation date: :29 June 2020
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